Bis[4-chloro-N′-(2-pyridylmethylidene)benzohydrazidato]cobalt(III) nitrate sesquihydrate
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چکیده
منابع مشابه
Sodium N-chloro-2-methylbenzenesulfonamidate sesquihydrate
In the title salt, Na(+)·C(7)H(7)ClNO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. The sodium ion shows an O(6) octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S-N distance of 1.5898 (19) Å is consistent with an S=N double bond. The crystal structure is stabilized by N-H⋯O and O-H⋯Cl hydrogen bonds.
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In the title compound, [Co(C(13)H(9)ClN(3)O)(2)]NO(3)·1.5H(2)O, the central Co(3+) atom in the cation is coordinated by four N and two O atoms from the two tridentate ligands in a distorted octa-hedral fashion. In the crystal, the cobalt complex cations are linked to the half-occupied and the fully occupied water mol-ecules, and the nitrate anion via classical inter-molecular O-H⋯O and O-H⋯N hy...
متن کاملSodium N,2-dichlorobenzenesulfonamidate sesquihydrate
In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. There is no inter-action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms from three different anions. The S-N distance of 1.588 (2) Å is consistent with an S=N double bond. The...
متن کاملPotassium N,2-dichlorobenzenesulfonamidate sesquihydrate
In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(-)·1.5H(2)O, one water mol-ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol-ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene-sulfonamide anions. The S-N distance of 1.582 (2) Å is consistent with an S-N double bond. In the structure, the sulfonyl-O and the wat...
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The title salt, C(7)H(9)ClNO(+)·NO(3) (-), exhibits extensive hydrogen bonding between the ammonium functional group and the nitrate anion. A two-dimensional network of bifurcated N-H⋯O hydrogen bonds generates corrugated layers in the bc plane. The organic mol-ecules are stacked in a parallel orientation as a result of π-π inter-actions, with an inter-ring distance of 3.837 Å.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s160053681004612x